Welcome to Dr. Kate Kraus Brilakis' Learning Portal
review question:
what is meant by the half life of an isotope? explain how isotopes are clinically useful.
Bonding:
atoms creating molecules
2. Covalent Bonds
= partial charge
General Chemistry
FYI... Carbon-14 decays into nitrogen-14 through a process called beta decay...a neutron within the carbon-14 nucleus transforms into a proton, an electron, and an electron antineutrino. This process increases the atomic number of the element from 6 (carbon) to 7 (nitrogen), while the mass number remains 14.
Oxygen exhibits a partial negative charge Hydrogen exhibits a partial positive charge.
if one atom is highly electronegative and the other less electronegative, the covalent bond will be polar
Bonding Types:
1. Ionic 2. Covalent 3. Hydrogen
Carbon
C and H have similar electronegativity
electrons are evenly shared
diagnostics:
*techniques like PET scans and bone scans to visualize internal organs, tissues, and structures, aiding in the detection of tumors, infections, abnormalities.
*tracer studies to track the movement and metabolism of isotope labelled molecules.
treatment:
* radiation therapy to deliver targeted doses of radiation to kill cancer cells and shrink tumors.
* certain isotopes treat specific conditions like hyperthyroidism. isotopes are taken up by the thyroid gland and destroy overactive cells.
There can be strong or weak acids and bases...
HCl is a strong acid because it dissociates almost completely in water releasing H+.
Acetic acid (CH3COOH...vinegar is 6% acetic acid in water) is a weak acid because it does not dissociate well in water.
Bases containing OH- are considered strong, like NaOH, because they also dissociate almost completely but they release OH-. what does that do to the pH? Why?
3. Hydrogen Bonds
review question:
describe the structure of an atom. explain why atoms bond with one another.
1. ionic bonds
A solvent is a substance that dissolves solute particles.
A solute is a substance that is dissolved by a solvent.
The outermost orbital shell of an atom is called its
valence shell.
the electrons in the valence shell are valence electrons.
Valence electrons are the highest energy electrons in an atom and are therefore the most reactive.
OH-
is a hydroxyl group
this sets up partially charged
"poles" in the molecule.
isotopes
review question:
what is an ion? how are ions made? why do ions bond together?
Na (sodium) atomic number = 11
Cl (chlorine) atomic number = 17
is it just about H+?
review question:
water is a universal solvent. why is this so important referencing living organisms?
pH
at pH 7
H+ and OH- concentrations are =
properties of water
Hydrogen bonds have about a tenth of the strength of an average covalent bond
clinical uses of radioisotopes
review question:
explain why the disassociation of water is an important factor in the pH of a solution.
Electron orbitals
predict where an electron might be at any given time. The number of orbitals increases as the atomic number increases.
octet rule:
atoms tend to gain, lose, or share electrons in order to achieve a full outer electron shell with eight valence electrons ibn order to achieve a stable electron configuration.
hydrogen bonds are strong intermolecular forces created when a hydrogen atom bonded to an electronegative atom (polar covalent bond) is attracted to a nearby electronegative atom.
It is important for cells/tissues maintain pH homeostasis.
The pH of the human body ranges between 7.35 to 7.45, with the average at 7.4
Oxygen is more electronegative than H
electrons are unevenly shared
nonpolar covalent bonds
An element's
atomic number (#protons/# electrons) is the number listed here at the upper left of each symbol. The atomic mass (#protons + # neutrons) is the number listed below the symbol.
pH 3 10*-3
has more H+ than pH 6 10*-6
in an aqueous solution,
as H+ concentration increases, OH- concentration decreases.
as just discussed, Carbon (C) has an atomic number = 6
atomic mass = 12.01
review question:
how is a polar covalent bond different from a non-polar covalent bond?
explain what causes atoms to engage in a polar covalent bond.
Carbon (C) has an atomic number or 6 and an atomic mass of 12.01
Hydrogen Bonds can only occur between two polar molecules. Why?
Carbon-14
is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Every 5,730 years, the radioactivity of carbon-14 decays by half which is called its half-life, a fact used during Carbon Dating.
isotopes are variations of elements that have the same number of protons but different numbers of neutrons.
The pH scale measures how much H+ is in a solution.
A lot of Hydrogen = low pH # = an acidic solution = an acid
less H+ = a higher pH = a basic (alkaline) solution = a base
polar covalent bonds
what do the pH numbers really mean?
review question:
in order for a hydrogen bond to occur between two molecules, both molecules must contain polar covalent bonds. explain why.
review question:
when dissolved in water...
citric acid has a pH of 3.
oxalic acid has a pH of 4
referencing the meaning of the pH numbers, explain which acid donates more H+ to the solution.
next up...
biologically relevant molecules ;)